acetoxypalladation

English

Noun

acetoxypalladation (plural acetoxypalladations)

1. (organic chemistry) A reaction in which an acetoxy group and a palladium atom are attached across a double bond (typically as the first step in another reaction)
   • 2015 July 22, Javier Mazuela, Debasis Banerjee, Jan-E. Bäckvall, “Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C–H Activation/Carbocyclization of Arylallenes”, in Journal of the American Chemical Society‎^[1], volume 137, →DOI:

     Measurements of deuterium kinetic isotope effects suggest that C–H bond breaking is not the rate-limiting step and that the acetoxypalladation of the allene moiety is the first irreversible step.